Name: Assignment I Class: X Subject: Chemistry
ATOMIC STRUCTURE
I. Choose the correct answer
1. The total number of electrons present in an orbit is given by ( )
(a) n2 (b) 2n2 (c) (2l + 1) (d) –l….,0,….,+l
2. The total number of orbitals present in any orbit is given by ( )
(a) n2 (b) 2n2 (c) (2l + 1) (d) –l….,0,….,+l
3. The total number of orbitals present in any given sub-shell is given by ( )
(a) n2 (b) 2n2 (c) (2l + 1) (d) –l….,0,….,+l
4. The energy values of orbitals present in any sub level is given by ( )
(a) n2 (b) 2n2 (c) (2l + 1) (d) –l….,0,….,+l
5. Bohr’s theory is valid for ( )
(a) All atoms (b) All ions (c) Any atom or ion having one electron
(d) All molecules
6. Who introduced stationary orbits ( )
(a) Bohr (b) Schrodinger (c) Zeeman (d) Sommerfeld
7. Who introduced elliptical orbits ( )
(a) Bohr (b) Rutherford (c) Max Planck (d) Sommerfeld
8. Which of the following shell has the least energy ( )
(a) L (b) M (c) K (d) N
9. Which of the following has the energy value ‘3’ ( )
(a) L (b) M (c) K (d) N
10. Sommerfeld proposed elliptical orbits to explain ( )
(a) Fine structure (b) Zeeman effect (c) Stark effect
(d) Absorption of electromagnetic radiation.
11. Which of the following quantum numbers give size and energy of stationary orbits?
(a) n (b) l (c) m (d) s
12. Which of the following quantum number gives shape of orbitals? ( )
(a) n (b) l (c) m (d) s
13. The sub shells present in L-shell are ( )
(a) s only (b) s,p and d (c) s,p,d and f (d) s and p
14. f-orbitals are present in ( )
(a) K (b) N (c) M (d) L
15. The energy value of orbital can be found by the rule of ( )
(a) 2n2 (b) n2 (c) (2l + 1) (d) (n + l)
16. The maximum value of l for a given value of n is given by ( )
(a) (2l + 1) (b) (n – 1) (c) –l….,o,….+1 (d) n2
17. The maximum value of l for n = 5 is ( )
(a) 5 (b) 3 (c) –5 (d) 4
18. The orbitals corresponding to energy value of 3 are ( )
(a) 2p (b) 3p (c) 4s (d) 5p
19. The planetary model of an atom was proposed by ( )
(a) Sommerfeld (b) Bohr (c) Rutherford (d) Newton
20. Out of the following, which element is having anomalous electronic configuration
(a) C (b) Cu (c) Ca (d) Co ( )
21. Out of the following, which element is having the highest electron affinity ( )
(a) F (b) Cl (c) Br (d) I
22. Electrons occupy the orbitals of lowest energy. This is known as ( )
(a) Pauli’s exclusion principle (b) Hund’s rule of maximum multiplicity
(c) Rutherford planetary model (d) Aufbau principle
23. Pairing of electrons takes place when all the degenerate orbitals are occupied by one electron each. This rule is known as ( )
(a) Pauli’s exclusion principle (b) Hund’s rule of maximum multiplicity
(c) Rutherford planetary model (d) Aufbau principle
24. No two electrons will have all the four quantum numbers the same. This rule is known as ( )
(a) Pauli’s exclusion principle (b) Hund’s rule of maximum multiplicity
(c) Rutherford planetary model (d) Aufbau principle
25. Out of the following which orbitals are symmetric ( )
(a) s (b) p (c) d (d) f
26. The electronic configuration [Ne] 3s1 corresponds to ( )
(a) H (b) K (c) Ca (d) Na
27. Quantum theory of radiation was proposed by ( )
(a) Pauli (b) Bohr (c) Max Planck (d) Sommerfeld
Name: Assignment I Class: X Subject: Chemistry
ATOMIC STRUCTURE
II Fill in the blanks
1. The electrons were discovered by ____________________
2. Planetary model (or) nuclear model of atom was proposed by _______________
3. Quantum theory of radiation was proposed by ____________________
4. The concept of stationary orbits was proposed by ____________________
5. The concept of elliptical orbits was proposed by ____________________
6. Principle quantum number was proposed by ____________________
7. Azimunthal quantum number was proposed by ____________________
8. Magnetic quantum number was proposed by ____________________
9. Spin quantum number was proposed by ____________________
10. The shape of orbitals is given by the quantum number ____________________
11. s-orbitals are ____________________ in shape.
12. p-orbitals are ____________________ in shape.
13. The shape of d orbitals is _______________.
14. Relative energies of orbitals are given by ____________________
15. The representation of occupation of electrons in the orbitals is known as _______________
16. The electronic configuration is La is _______________
17. According to ________________ the electrons occupy the orbitals of lowest energy.
18. The orbitals having the same energy are known as _______________
19. The electronic configuration of Cr is ____________________
20. The electronic configuration of cu is ____________________
21. Ionisation energy is measured in ____________________
22. Electron affinity is measured in ____________________
23. The second ionization energy is always ___________ than the first ionization energy
24. Bohr proposed atomic theory based on ____________________
25. Angular momentum of revolving electron in a stationary orbit is _____________ h/2Ï€
26. The location of an electron in an atom is given by ____________________
27. After filling the 3d orbitals, the electron enters into _______________ orbital.
28. After filling the 3p orbitals, the electron enters into _______________ orbital.
29. 3d10 4s1 is the valence electronic configuration of ________________
30. 3ds 4s1 is the valence electronic configuration of ____________________
31. The number of nodal regions present in any ‘ns’ orbital is given by the formula _______________
III 1 Mark questions
1. What are the fundamental (sub-atomic) particles present in the atom?
A. Electrons, protons and neutrons are the fundamental particles present in the atom.
2. What are nucleons?
A. Protons and neutrons are called as nucleons as they are present in the nucleus of an atom.
3. Who discovered electrons?
A. J.J. Thomson discovered electrons in 1903.
4. What is Max Planck’s quantum theory of radiation?
A. According to Max Planck’s quantum theory, the electromagnetic radiation is absorbed by matter not continuously but discontinuously in the form of packets of energy called ‘quanta’.
5. Write Planck’s equation?
A. E = h is the Plank’s equation, E is the energy absorbed or emitted
is the frequency of radiation h is the Plank’s constant
6. What is the value of Planck’s constant?
A. The value of the Planck’s constant is 6.625 x 10-27 erg.sec
7. What is the basic for Bohr’s model of an atom?
A. Max Planck’s quantum theory of radiation is the basic for Bohr’s model of an atom.
8. What is a stationary orbit?
A. As the energy of the electrons revolving in certain specified paths remains stationary, they are called as stationary orbits.
9. What are different stationary orbits?
A. The different stationary orbits as proposed by Bohr are K, L, M, N, etc.,
10. What information does the prinicpal quantum number give?
A. Principal quantum number gives information about size and energy of orbits.
11. Who proposed the principal quantum number?
A. Niels Bohr proposed the principal quantum number.
12. Why the angular momentum of an electron is said to be quantized?
A. The electron revolving in the orbits, can accept only certain specified values like 1 h/2Ï€, 2 h/2Ï€, 3 h/2Ï€, 4 h/2Ï€ … etc. Hence the angular momentum of the electron is said to be quantized.
13. What are degenerated orbitals?
A. The orbitals, present in a particular sub level, having the same energy are called as degenerate orbitals.
14. Who introduced elliptical orbits?
A. Sommerfeld introduced elliptical orbits.
15. Who introduced the Azimuthal quantum number?
A. Sommerfeld introduced the Azimuthal quantum number.
16. What are the limits of Azimuthal quantum number for a given value of ‘n’?
A. For a given ‘n’ the Azimuthal quantum number values are 0,1, … (n-1) i.e the highest value is (n –1)
17. Who introduced the magnetic quantum number?
A. Lande introduced the magnetic quantum number.
18. On what values, the values of ‘m’ depend?
A. The values of ‘m’ depend upon the value of l. The number of possible values (orientations) are (2l + 1) and the energy values are given by –l, -l + 1, ….0….(l-1), l etc.
19. How many m values are possible for l = 3?
A. If l = 3, then 2l + 1 = 7. Hence seven values are possible for l = 3.
20. What are the different values of m for l = 3?
A. For l = 3, the different values of m are –3, -2, -1, 0, 1, 2, 3.
21. What are the different values of m for l = 2?
A. For l = 2, the different values of m are –2, -1, 0, 1, 2.
22. What are the upper and lower limits of m for l = 4.
A. The upper limit is +4 and the lower limit is –4.
23. What are the upper and lower limits of m for l = 2.
A. The upper limit is +2 and the lower limit is –2
24. What happens to the orbitals of an atom in the presence of magnetic filed.
A. In the presence of magnetic field, the degenerate orbitals orient in different directions. The number of possible orientations are given by the formula (2l + 1)
25. Who introduced the spin quantum number?
A. Unlenbeck and Goudsmith introduced the spin quantum number in 1925
26. What are quantized values of spinning electron?
A. +1/2 and –1/2 are the only quantized values of spinning electron.
27. What is the necessary condition for the pairing of electrons in the same orbital?
A. The necessary condition for pairing of electrons in the same orbital is that they must possess opposite spins.
28. Define atomic orbital?
A. Atomic orbital is the region in space around the nucleus where there is a finite probability of finding the electron.
29. What is a nodal region?
A. The region around the nucleus, where the probability of finding the electron is zero, is called nodal region.
30. How many nodal regions are present in 4s orbital?
A. Since n =4, n-1 = 4-1 = 3, Hence three nodal regions are present in 4s orbital.
31. Write the designations of three P orbitals?
A. Px, Py, Pz are the designations of three P orbitals
32. Write the designations of all five d orbitals?
A. dxy, dyz, dzx, dx2 – y2, dz2 are the designations of all five d orbitals.
33. what is the electronic configuration?
A. Electronic configuration is the representation of the occupation of electrons in the orbitals.
IV 2 marks questions
1. Explain the presence of lines in the hydrogen spectrum?
2. Write the electronic configuration of Cr? Explain the anomaly?
3. Write the electronic configuration of Cu. Explain the anomaly?
4. State Aufbau principle?
5. What is Pauli’s exclusion principle?
6. State Hund’s rule?
7. Define atomic radius?
8. Write about atomic radius?
9. Define ionization energy? On what factors, it depends?
10. Define electron affinity?
11. Why the EA of F is less than that of CI?
VI 4 Marks questions
1. Write the important features of Rutherford’s planetary model?
2. What are the defects of Rutherford’s model?
3. State the postulates of Bohr’s model?
4. What are the defects of Bohr’s atomic model?
5. Discuss the features of modern atomic structure pertaining to the nucleus and stationary states.
6. State and explain with one example the Aufbau principle.
7. State and explain with one example the Hund’s rule of maximum multiplicity.
8. Define ionization energy and mention factors that influence it?
VII 5 Marks questions
1. Draw the shapes of ‘S’ and ‘P’ orbitals
2. Draw the shapes of five d orbitals
3. Draw the diagram showing the sequence of filling up of various atomic orbitals.
4. Draw the diagram showing Bohr’s model of atoms.
5. Draw the diagram showing the Sommerfeld’s elliptical orbits for n = 4.